2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 1: Aifantis Intl. Symp. / Multiscale Material Mechanics

Editors:Kongoli F, Bordas S, Estrin Y
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:300 pages
ISBN:978-1-987820-24-9
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2015_Volume
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    Zr-catalyzed Asymmetric Carboalumination of Alkene (ZACA) for Highly Selective Syntheses of Various Fine Organic Compounds

    Ei-ichi Negishi1;
    1PURDUE UNIVERSITY, West Lafayette, United States;
    Type of Paper: General Plenary
    Id Paper: 569
    Topic: 42

    Abstract:

    The challenge of a Green Chemistry today in the organic world is to synthesize organic materials in high yields, efficiently, selectively, economically and safely. This is achieved by using theoretically all usable pure elements (around 70) avoiding radioactive, inert and inherently toxic elements and their binary combinations (around 5000). Metals play here an important role because of their desirable reactivities while transition metals play a magical role as catalysts because of their simultaneous availability of empty and filled non-bonding orbitals among other properties. As an example of this magical role it is described the influence of Zr as a catalyst for the asymmetric carboalumination of alkene in the highly selective synthesis of various fine organic components.

    Cite this article as:

    Negishi E. Zr-catalyzed Asymmetric Carboalumination of Alkene (ZACA) for Highly Selective Syntheses of Various Fine Organic Compounds. In: Kongoli F, Bordas S, Estrin Y, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 1: Aifantis Intl. Symp. / Multiscale Material Mechanics. Volume 1. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 37-38.