2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 11: Recycling & Environmental

Editors:Kongoli F, Havlik T, Pagnanelli F
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:410 pages
ISBN:978-1-987820-34-8
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    Silicon Photovoltaic Panels: Characterization and Recycling Possibilities

    Pablo Dias1; Mariana Goncalves Benevit1; Hugo Marcelo Veit1; Andrea Moura Bernardes1;
    1UFRGS, Porto Alegre, Brazil;
    Type of Paper: Regular
    Id Paper: 12
    Topic: 7

    Abstract:

    The growing demand for energy combined with the scarcity of non-renewable energy sources has led to the research of alternative energy sources capable of replacing the traditional ones with the least environmental impact. Among these alternatives, solar energy is very important, since it is a virtually inexhaustible source and generates relatively small environmental impact compared to other traditional generation sources. The collection of solar energy and its conversion into thermal or electrical energy is only possible with photovoltaic panels. These panels have a limited lifespan of 20 -25 in average and will eventually be replaced by new ones and thrown away. Thus, in the near future, large amounts of solar modules will become electronic waste. In order to retrieve important raw materials, reducing production costs of new panels and environmental impacts, recycling such materials is important. <br />In this paper, photovoltaic module components were characterized through visual inspection, x-ray fluorescence, energy dispersion spectroscopy and atomic absorption spectroscopy. The glass was identified as ordinary glass (soda-lime glass), which can be reused without any previous treatment. The metallic filaments were identified as tin-lead coated copper, which can be recycled through known pyrometallurgical processes. The modules' cells were made of silicon and had silver filaments attached to it. The silicon and silver were separated and recovered through chemical processes. The modules' frames were identified as aluminium and can be recycled without any previous treatment. <br />Moreover, different segregation methods have been studied in order to separate the different components with the smallest environmental impact. Chemical, pyrometallurgical and mechanical methods have been tested. Pyrometallurgical methods have shown the most promising results so far. A detailed description of the separations methods and the experiments' layouts will be given.

    Keywords:

    Photovoltaic panels; Recycling; Pyro pre-treatment; chemical component's separation

    References:

    [1] International energy agency (2013): Photovoltaic power systems programme – trends 2013 in photovoltaic applications
    [2] European commission, jrc scientific and policy report (2013): PV status report – Luxembourg
    [3] Pern J., (2008): Module encapsulation materials, processing and testing – APP international PV reliability workshop – Shanghai, China
    [4] Brouer K., Gupta C., Honda S., Zargarian M. (2011): Methods and concerns for disposal of photovoltaic solar panels - Project Report (Master of Science In Engineering) - San Jose State University, San Jose
    5Radziemska E.K., Ostrowski P. (2010): Chemical treatment of crystalline silicon solar cells as a method of recovering pure silicon from photovoltaic modules – Renewable Energy, 35: 1751-1759
    [6] Frisson L., Lieten K., Bruton T., Declercq K., Szlufcik J., De Moor H., Goris M., Benali O., Aceves O. (2000): Recent improvements in industrial PV module recycling – European photovoltaic solar energy conference – Glasgow, United Kingdom
    [7] Giacchetta G., Leporini M., Marchetti B. (2013): Evaluation of the environmental benefits of new high value process fot the management of the end of life of thin film photovoltaic modules – Journal of cleaner production, 51: 214-224
    [8] Mcdonald N.C., Pearce J.M. (2010): Producer responsibility and recycling solar photovoltaic modules – Energy Policy, 38: 7041-7047
    [9] ASTM E1131 (2014): Standard Test Method for Compositional Analysis by Thermogravimetry – Book of Standards Volume: 14.02; Available at: http://www.astm.org/Standards/E1131.htm

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    Cite this article as:

    Dias P, Goncalves Benevit M, Veit H, Moura Bernardes A. Silicon Photovoltaic Panels: Characterization and Recycling Possibilities. In: Kongoli F, Havlik T, Pagnanelli F, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 11: Recycling & Environmental. Volume 11. Montreal(Canada): FLOGEN Star Outreach. 2015. p. 333-340.