2015-Sustainable Industrial Processing Summit
SIPS 2015 Volume 4: Meech Intl. Symp. / Mining Operations

Editors:Kongoli F, Veiga MM, Anderson C
Publisher:Flogen Star OUTREACH
Publication Year:2015
Pages:275 pages
ISBN:978-1-987820-27-0
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2015_Volume
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    Assessment of Hexavalent Chromium in Ground Water of Chromite Mines at Sukinda Valley, Odisha, India

    Soumya Ranjan Mishra1;
    1GUJARAT INSTITUTE OF DESERT ECOLOGY, Bhuj, Kachchh, India;
    Type of Paper: Regular
    Id Paper: 314
    Topic: 4

    Abstract:

    Sukinda Valley, the 4th most polluted region in the world, present in the triangular sketch of Jajpur, Dhenkanal and Keonjhar district of Odisha state, contributes to around 97% of the total chromium deposits in India. Among the 17 mining leases in the valley, 13 are operational. Of the 13 operational mines, 11 are opencast and rest underground. The extensive production of chromite has led to the contamination of surface and ground water of the valley. Between the stable atomic states of chromium i.e., Cr(III) and Cr(VI), the later one is harmful and carcinogenic in nature. Around 2.3 million people are affected by the hexavalent chromium contaminated water in Sukinda Valley. Thus, we undertook a study to assess the concentration of Cr(VI) in and around the mining areas of Sukinda Valley. The present study provides a detailed information regarding the groundwater contamination due to extensive mining activity and mitigation measures from the hazards of Cr(VI). I collected 103 ground water samples from various water consumption sources viz., open wells, bore wells and tube wells within the mine lease area. The samples were analysed for Cr(VI) following diphenylcarbazide method. The Cr(VI) varied from 0.004mg/L to 0.652mg/L. All the collected samples contained Cr(VI). However, 15 samples exceeded the permissible limits of 0.05mg/L prescribed by Central Pollution Control Board (CPCB), India. The sustainable chromite mining in the valley is a major issue so far as the concentration of Cr(VI) is concerned. The production strategies in the mining need to be modified and mining activity below the ground water table should be done by following advanced and sustainable mining techniques. All mine leases in Sukinda Valley need to make a combined effort for sustainable mining and prevent ground water contamination by the carcinogenic Cr(VI).

    Keywords:

    Chromite, Ground water, Hexavalent chromium, Mining, Sukinda valley.

    References:

    [1] M. C. Moncur, C. J. Ptacek, D. W. Blowes, J. L. Jambor, Release, transport, and attenuation of metals from an old tailings impoundment. Appl. Geochem. (2005), 20, 639&#8722;659.
    [2] R. Dhakate, V. S. Singh, Heavy metal contamination in groundwater due to mining activities in Sukinda valley, Odisha—A case study [J]. Journal Geography and Regional Planning, (2008), 1(4): 58&#8722;67.
    [3] A. Basu, R. Saha, J. Mandal, S. Ghosh, B. Saha, Removal of hexavalent chromium by an aromatic alcohol. Journal of Biomedical Science Engineering, (2010), 3, 735&#8722;741.
    [4] B. Saha, C. Orvig, Biosorbents for hexavalent chromium elimination from industrial and municipal effluents. Coordination Chemical Revolution (2010), 254, 2959&#8722;2972.
    [5] S.P.B. Kamaludeen, M. Megharaj, A.L. Juhasz, N. Sethunathan, R. Naidu, Chromium microorganism interactions in soils: remediation implications, Rev. Environment Contamination Toxicology 178 (2003) 93–164.
    [6] D. F. Ackerley, Y. Barak, S. V. Lynch, J. Curtin and A. Matin, “Effect of Chromate Stress on Escherichia coli K-12,” Journal of Bacteriology, Vol. 188, No. 9, May 2006, pp. 3371-3381
    [7] D. Bagchi, S. J. Stohs, W. O. Bernard, M. Bagchi and H. G. Preus, “Cytotoxicity and Oxidative Mechanism of Different Forms of Chromium,” Toxicology, Vol. 180, No. 1, October 2002, pp. 5-22.
    [8] K. H. Cheung and J. D. Gu, “Mechanism of Hexavalent Chromium Detoxification by Microorganisms and Bioremediation Application Potential: A Review,” International Biodeterioration & Biodegradation, Vol. 59, No. 1, January 2007, pp. 8-15.
    [9] A. Baral, D. Robert, R. D. Engelken, Chromium-based regulations and greening in metal finishing industries in the USA. Environmental Science Policy, (2002), 5, 121&#8722;133.
    [10] H. Mishra and H. B. Sahu, Environmental Scenario of Chromite Mining at Sukinda Valley – A Review, International Journal of Environmental Engineering and Management, ISSN 2231-1319, Volume 4, Number 4 (2013), pp. 287-292.
    [11] Blacksmith Institute, The World’s Worst Polluted Places – 2007, Blacksmith Institute, New York.
    [12] A. Das, and S. Mishra, Biodegradation of the metallic carcinogen hexavalent chromium Cr (VI) by an indigenously isolated bacterial strain, Journal of Carcinogen, (2010), Vol.9, No.6, pp 19-24.
    [13] R. B. Panda, S. Pattnaik and D. K. Pattnaik, (2012) Environmental Scenario of Chromite ore mining at Sukinda Valley Beyond 2030, International Journal of Discovery Science, (2012), 1(2), 35-39.
    [14] G.R.C. Cooper, Oxidation and toxicity of chromium in ultramafic soils in Zimbabwe, Applied Geochemistry 17 (8) (2002) 981–986.
    [15] APHA, AWWA, WEF, Standard methods for the examination of water and waste water, 20th American Public Health Association, American Water Works Association, Water Environment Federation (1998).
    [16] S.K. Sharma, B. Petrusevski & G. Amy, Chromium Removal from Water: A Review, Journal of Water Supply: Research and Technology - AQUA, (2008), 57:8:541.
    [17] L.E. Eary, & D. Rai, Chromate Removal from Aqueous Wastes by Reduction with Ferrous Iron. Environmental Science and Technology, (1988), 22:8:972.
    [18] P. Brandhuber, M.M. Frey, M.J. McGuire, P.-F. Chao, C. Seidel, G. Amy, J. Yoon, L.S. McNeill, & K. Banerjee,. Low-Level Hexavalent Chromium Treatment Options (2004): Bench-Scale Evaluation, AWWARF, Denver CO.
    [19] D. Clifford, S. Subramonian, & T.J. Sorg, Water Treatment Processes III. Removing Dissolved Inorganic Contaminants from Water. Environmental Science & Technology, (1986), 0:11:1072.
    [20] J.G. Hering, & T.C. Harmon, Geochemical Controls on Chromium Occurrence, Speciation, and Treatability, AWWARF, (2004), Denver CO.
    [21] G. Lee, & J. G. Hering, Removal of Chromium(VI) from Drinking Water by Redox- Assisted Coagulation with Iron(II).
    [22] G. Qin, M. J. McGuire, N. K. Blute, Seidel, C. & Fong, L., 2005. Hexavalent Chromium Removal by Reduction with Ferrous Sulfate, Coagulation, and Filtration: A Pilot-Scale Study. Environmental Science & Technology, (2012), 39:16:6321.
    [23] J.A. Drago, Technology and Cost Analysis for Hexavalent Chromium Removal from Drinking Water Supplies, AWWA Water Quality and Technology Conference, (2001), Nashville, TN.
    [24] J. Yoon, G. Amy, J. Chung, J. Sohn, J. & Y. Yoon, 2009. Removal of Toxic Ions (Chromate, Arsenate, and Perchlorate) Using Reverse Osmosis, Nanofiltration and Ultrafiltration Membranes. Chemosphere, (2002), 77:2:228.
    [25] J. Yoon, G. Amy, & Y. Yoo, Transport of Chromium (Cr(VI)) through Reverse Osmosis (RO), Nanofiltration (NF) and Ultrafiltration (UF) Membranes, AWWA Annual Conference and Exposition, New Orleans, LA.
    [26] N. K. Blute, & Y. Wu, Chromium Research Effort by the City of Glendale California (Interim Report), Arcadis U.S. Inc., Los Angeles, CA.
    [27] H. Lai, & L.S. McNeill, Chromium Redox Chemistry in Drinking Water Systems. Journal of Environmental Engineering, (2006) 132:8:842.
    [28] G. H. Lee, & J.G. Hering, Oxidative Dissolution of Cr(III) Hydroxide at pH 9, 3, and 2 with Product Inhibition at pH 2. Environmental Science & Technology, (2005), 39:13:4921.
    [29] C. R Evanko, and D.A Dzombak,. Remediation of Metals-Contaminated Soil and Groundwater. Ground-Water Remediation Technologies Analysis Center (GWRTAC) Office of Solid Waste and Emergency Response Technology Innovation. U.S. Environmental Protection Agency Washington, (1997) DC, pp. 61.
    [30] M.E.H. Ala Eldin, M. Sami Ahmad, R. Gurunadha, R.L. Dhar: Groundwater Modelling In Parts of Central Ganga Basin, Uttar Pradesh, India. (1998), Technical Report. No. AMU/NGRI-1, Collaborative Project between Remote Sensing Application for Evaluation and Geo-Engineering, Aligarh and NGRI.
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    Cite this article as:

    Mishra S. Assessment of Hexavalent Chromium in Ground Water of Chromite Mines at Sukinda Valley, Odisha, India. In: Kongoli F, Veiga MM, Anderson C, editors. Sustainable Industrial Processing Summit SIPS 2015 Volume 4: Meech Intl. Symp. / Mining Operations. Volume 4. Montreal(Canada): FLOGEN Star Outreach. 2015. p. .