2016-Sustainable Industrial Processing Summit
SIPS 2016 Volume 6: Yagi Intl. Symp. / Metals & Alloys Processing

Editors:Kongoli F, Akiyama T, Nogami H, Saito K, Fujibayashi A
Publisher:Flogen Star OUTREACH
Publication Year:2016
Pages:480 pages
ISBN:978-1-987820-46-1
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2016_Volume1
CD shopping page

    Enrichment and Recovery Fe-containing Phases from High Iron Gibbsite Ore Based on Metallized Reduction and Magnetic Separation

    Zhenggen Liu1; Mansheng Chu1; Wei Zhao1; Hongtao Wang1; Zheng Wang1; Jue Tang1; Cong Feng2; Yating TANG1;
    1NORTHEASTERN UNIVERSITY, Shenyang, China; 2, Shenyang, China;
    Type of Paper: Regular
    Id Paper: 41
    Topic: 3

    Abstract:

    High iron gibbsite ore is a complex composition and microstructure ore, which features high iron content, high silica content, low alumina content and low A/S. In order to recover iron from high iron gibbsite ore, the process of metallized reduction and magnetic separation based on hot briquette agglomerates was researched systemically. The effect of reduction temperature, reduction time, and the mole ratio of fixed carbon to reducible oxygen (FC/O) on separation indexes was researched. The results show that, with the conditions of reduction temperature 1350¡æ, reduction time 70 min, FC/O 1.0, and magnetic field intensity of 50 mT, about 87.01% of the iron could be removed from high iron gibbsite ore as metallic iron. Meanwhile, 86.21% of the aluminum are staying in a non-magnetic fraction as alumina. The phase transition of iron-bearing minerals during reduction process are obtained as follows: Fe2O3 ¡u FeO (FeO¡¤Al2O3) ¡u Fe. The experiments and thermomechanical analysis show that the formation of hercynite (FeAl2O4) limits the reduction rate of iron oxides to metallic iron. A higher recovery ratio of iron could be achieved by adding the catalyst.

    Keywords:

    Extraction; Iron; Metallurgy; Process; Recovery;

    References:

    [1] C.A. Pickles, T. Lu, B. Chambers and J. Forster: A study of reduction and magnetic separation of iron from high iron bauxite ore, Canadian Metallurgical Quarterly, 51(2012), 424-433.
    [2] Z.F. Liu: Overview of world bauxite resource, Light Metals, (2001), 7-12.
    [3] P.P. Cui, Z.M. Huang and S.L. Zhou. Overview of bauxite resources in China, Light Metals, (2008), 6-8.
    [4] X.H. Mu: Discussion on reasonable exploitation of bauxite mineral resources in China, Mineral Resources and Geology, 16(2002), 313-315.
    [5] P. Bolsaitis and V. Chang: Process parameters in mineral separation by HGMS: purification of bauxite, IEEE Transaction on Magnetics, 17(1981), 3311-3313.
    [6] L.Y. Sadler and C. Venkataraman: A process for enhanced removal of iron from bauxite ore, International Journal of Mineral Processing, 31(1991), 233-246.
    [7] R.B. Rao, L. Besra, B.R. Reddy and G.N. Banerjee: The effect of pretreatment on magnetic separation of ferruginous minerals in bauxite, Magnetic and Electrical Separation, 8(1997): 115-123.
    [8] G.N. Banerjee, B.R. Reddy and R.B Rao: Deironation of bauxite by gaseous reduction and magnetic separation for refractory uses, Transactions of the Indian Institute of Metals, 53(2000): 527-529.
    [9] G Patermarakis and Y Paspaliaris: The leaching of iron oxides in boehmitic bauxite by hydrochloric acid, Hydrometally, 23(1989), 77-90.
    [10] Y Paspaliaris and Y Tsolakis: Reaction kinetics for the leaching of iron oxides in diasporic bauxite from the parnassus-giona zone (Greece) by hydrochloric acid, Hydrometally, 19(1987): 259-266.
    [11] R.D. Holliday and D.J. Milne: Experimental evaluation of routes for purification of bauxite by gas-solid reactions. Industrial & Engineering Chemistry Process Design and Development, 14(1975), 447-452.
    [12] I Szabo, A Ujhidy, R Jelinko, and I Vassamyi: Decrease of iron content of bauxite through high - temperature chlorination, Hungarian Journal of Industrial Chemistry, 17(1989), 465-475.
    [13] Y.T. Li, S.W. Bi, Z.Y. Duan, Y.H. Yang, and J.D. Zhang: Discussion on the comprehensive utilization technology of high iron gibbsite ore in Guigang city Guangxi region, Light Metals, (1992), 6-14.
    [14] T. Lu, C.A. Pickles and S. Kelebek: Carbothermal reductive upgrading of a bauxite ore using microwave radiation, High temperature Materials and Process, 31(2012), 139-148.
    [15] Z.G. Liu, M.S. Chu, Z. Wang, W. Zhao and J. Tang: Study on metallized reduction and magnetic separation of iron form fine particles of high iron bauxite ore, High temperature Materials and Process, DOI: 10.1515/htmp-2015-0005.
    [16] A Kasai, Y. Mastsui, F. Noma, H. Iwakiri and M. Shimizu: Cold strength enhancement mechanism of carbon composite iron ore hot briquet, Tetsu to Hagane, 87(2001), 313-319.
    [17] M.S. Chu, Z.G. Liu, Z.C. Wang and J. Yagi: Fundamental study on carbon composite iron ore hot briquette using as blast furnace burden, Steel Research International, 82(2011), 521-528.
    [18] M. Chu, Z.C. Wang, Z.G. Liu and J.P. Lv: Experimental study on controlling step of self-reduction process of carbon composite iron ore hot briquette, The Chinese Journal of Process Engineering, 10(2010), 121-126.
    [19] M. Chu, H. Nogami and J. Yagi: Numerical analysis on charging carbon composite agglomerates into blast furnace, ISIJ International, 44(2004), 510-517.
    [20] S.Y. Chen and M.S. Chu: Metalizing reduction and magnetic separation of vanadium titano-magnetite based on hot briquetting, International Journal of Minerals, Metallurgy and Materials, 21(2014), 225-233.
    [21] G.H. Li, M.D. Liu, T. Jiang, T.H. Zhou and X.H. Fan: Mineralogy characteristics and separation of aluminum and iron of high-aluminum iron ores, Journal of Central South University (Science and Technology), 2009, 40(5): 1165-1171
    [22] Z.G Liu, Z. Wang, J. Tang, H.T Wang and H.M. Long: Non-isothermal thermal decomposition kinetics of high iron gibbsite ore based on Popescu method. Transactions of Nonferrous Metals Society of China, 25(2015), 2415-2421.
    [23] X. Jiang, F.M. Shen, L.G. Liu, X.G. Li and L. Wang: Experimental investigation on direct reduction followed by magnetic separation for Nb2O5-bearing ore, ISIJ International, 53(2013), 1358-1364.
    [24] M.S. Chu, Z.C. Wang, M.X. Ai and Z.G. Liu: Experimental study on cold strength of carbon composite iron ore hot briquette, Journal of Northeastern University (National Science), 30(2009), 696-700.
    [25] Z.G. Liu, M.S. Chu, Z. Wang and H.T. Wang: Influencing factors optimization on the compressive strength of high iron bauxite hot briquettes with response surface methodology, Journal of Northeastern University (National Science), 36(2015), 1278-1282.
    [26] G. Wang, J.S. Wang, Y.G. Ding, S. Ma and Q.G. Xue: New separation method of boron and iron from ludwigite based on carbon bearing pellet reduction and melting technology, ISIJ International, 52(2012), 45-51.

    Full Text:

    Click here to access the Full Text

    Cite this article as:

    Liu Z, Chu M, Zhao W, Wang H, Wang Z, Tang J, Feng C, TANG Y. Enrichment and Recovery Fe-containing Phases from High Iron Gibbsite Ore Based on Metallized Reduction and Magnetic Separation. In: Kongoli F, Akiyama T, Nogami H, Saito K, Fujibayashi A, editors. Sustainable Industrial Processing Summit SIPS 2016 Volume 6: Yagi Intl. Symp. / Metals & Alloys Processing. Volume 6. Montreal(Canada): FLOGEN Star Outreach. 2016. p. 278-289.