2016-Sustainable Industrial Processing Summit
SIPS 2016 Volume 8: Non-ferrous, Rotary Kiln, Ferro-alloys, Rare Earth, Coal

Editors:Kongoli F, Xueyi G, Shumskiy V, Kozlov P, Capiglia C, Silva AC, Turna T
Publisher:Flogen Star OUTREACH
Publication Year:2016
Pages:350 pages
ISBN:978-1-987820-50-8
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2016_Volume1
CD shopping page

    Receiving The Qualitative Rutile Concentrate From Sub-Standard Titanium Slag

    Madali Naimanbayev1; Nina Lokhova1; Zhazira Baltabekova2; Galymzhan Maldybaev3; A. E. Abisheva4;
    1CENTER OF EARTH SCIENCES, METALLURGY AND ORE BENEFICATION, Almaty, Kazakhstan; 2CENTER OF EARTH SCIENCES, METALLURGY AND ORE BENEFICATION, Almaty, Kazakhstan, Kazakhstan; 3KAZAKH NATIONAL RESEARCH TECHNICAL UNIVERSITY, Almaty, Kazakhstan; 4JSC "CENTER OF EARTH SCIENCES, METALLURGY AND ENRICHMENT", Almaty, Kazakhstan;
    Type of Paper: Regular
    Id Paper: 158
    Topic: 6

    Abstract:

    Integrated utilization of natural resources using energy-saving and waste-free technologies is relevant around the world. This applies to such type of raw material as titanium-magnetite ore. Shortage of ilmenite raw materials in the Republic of Kazakhstan for titanium slag melting challenges the search of alternative titanium-containing raw materials, titanomagnetites in particular. At the same time, there are deposits of indigenous titanomagnetite ores (Velikovskoe, Tymlay, Masalskoe, etc.) of huge reserves, which can become the complex raw material for production of iron, titanium and vanadium. Tymlay field in the South-Eastern part of Chu-Ili watershed is of particular interest, within the Karasay ore unit with iron content of 30,4 and titanium dioxide - 10%, and after beneficiation titano-magnetite concentrate contains Fe-52,4; TiO2-of 16,06%. Technology of titanium-magnetite concentrate ore-thermal melting was developed at Tymlay deposit producing hot metal and low titanium slag that can become the raw material for titanium production using chloride method. Slag produced in course of titanomagnetite ore-smelting consists mainly of alumosilicates and sodium silico titanates, magnesium and calcium titanates, titanium dioxide and lower titanium oxides. In this regard, chemical beneficiation is the main task of researchers handling the problem of low titanium slag processing. Following operations were carried out to improve titanium slag quality: slag sintering with sodium hydroxide; cake leaching with water to remove water-soluble impurities; to reduce the number of operations impurities leaching with hydrochloric acid was combined with pyrohydrolysis of titanic acid; rutile concentrate production (85% TiO2, 7,66% SiO2), silica removal by means of sodium hydroxide solution treatment, finally sellable rutile concentrate was produced with titanium dioxide 91-92% and silica 1,7 to 2,0% content. Based on research results technological scheme of titano-magnetite concentrate processing at Tymlay deposit was proposed producing hot metal and certified rutile concentrate, suitable for chlorination.

    Keywords:

    Non-Ferrous; Processing; Slag; Technology; Titanomagnetite; Titanium slag; Chemical beneficiation; Titanium dioxide; Rutile;

    References:

    [1] Reznichenko V. A., Karyasin I. A., Morozov A. A., Sadykhov G. B. Complex use of titanomagnetites in the new stage of production development. Journal Metals, № 6. рp. 3-8. 2000.
    [2] Sadykhov G. B. Development of scientific bases and technology for complex use of titanomagnetites of high titanium dioxide content: Abstrakt of the dissertation of Phd. Moscow, 2001.
    [3] Patent 1414782 RU. Method of synthetic rutile production out of titanomagnetites enriched titanium products / Z. I. Alizade, G. B. Sadykhov, A. M. Gusein-zade; publ. 07.08.1988, bull. No. 29. – 5 p.
    [4] Vodopiyanov A. G., Kozhevnikov G. N. Development of titanium dioxide recovery processes from the slag and leucoxene raw materialsю Proceedings of Intern. Congress "Fundamental basis of technologies of technogenic wastes processing and recycling ". Ekaterinburg, 2012. рp. 338-340.
    [5] Tianyan Xue, Lina Wang, Tao Qi, Jinglong Chu, Jingkui Qu, Changhou Liu. Decomposition kinetics of titanium slag in sodium hydroxide system. Hydrometallurgy 95. 2009. pp. 22-27.
    [6] Scott Middlemas, Z. Zak Fang, Peng Fan. A new method for production of titanium dioxide pigment. Hydrometallurgy 131-132. 2013. pp. 107-113.
    [7] Arao J. Manhigue, Walter W. Focke, Carvalho Madivate. Titania recovery from low-grate titanoferrous minerals. Hydrometallurgy 109. 2011. pp. 230-236.
    [8] Wang Dong, Chu Jinglong, Lijie, Qi Tao, Wang Weijing. Anti-caking in the production of titanium dioxide using low-grade titanium slag via the NaOH molten salt method. Powder technology 232. 2012. pp. 99-105.
    [9] Vyazowiecki Y. V., Karepov S. V., Ivanchuk V. A., Kovalevsky A. F. Tymlay ore field - new raw material base of titanium-magnetite ores in Kazakhstan. /Izvestiya NAN RK. Geological series. 2009. № 3. рр. 40-49.
    [10] Ni L. P., Raizman V. L. Combined methods of substandard aluminum raw material processing. Alma-Ata: Nauka. 1988. 256 p.
    [11] Lasheen T.A. Soda ash roasting of titania slag product from Rosetta ilmenite. Hydrometallurgy 93. 2008. рр. 124-128.

    Full Text:

    Click here to access the Full Text

    Cite this article as:

    Naimanbayev M, Lokhova N, Baltabekova Z, Maldybaev G, Abisheva A. Receiving The Qualitative Rutile Concentrate From Sub-Standard Titanium Slag. In: Kongoli F, Xueyi G, Shumskiy V, Kozlov P, Capiglia C, Silva AC, Turna T, editors. Sustainable Industrial Processing Summit SIPS 2016 Volume 8: Non-ferrous, Rotary Kiln, Ferro-alloys, Rare Earth, Coal. Volume 8. Montreal(Canada): FLOGEN Star Outreach. 2016. p. 79-88.