2017-Sustainable Industrial Processing Summit
SIPS 2017 Volume 7. Recycling, Secondary Batteries and Environmental Protection

Editors:Kongoli F, Aifantis K, Kumar V, Pagnanelli F, Kozlov P, Xueyi G
Publisher:Flogen Star OUTREACH
Publication Year:2017
Pages:205 pages
ISBN:978-1-987820-73-7
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    Recycling of Lithium Ion Batteries: Mechanical and Hydrometallurgical Treatment Towards Zero-waste

    Emanuela Moscardini1; Pietro Altimari2; Luigi Toro2; Thomas Abo Atia2; Francesca Pagnanelli3; Flavia Carla dos Santos Martins Padoan3;
    1SAPIENZA UNIVERSITY, Roma, Italy; 2SAPIENZA UNIVERSITY, Rome, Italy; 3SAPIENZA UNIVERSITY OF ROME, Rome, Italy;
    Type of Paper: Regular
    Id Paper: 330
    Topic: 7

    Abstract:

    In this work, the overall process for the treatment of LIB was presented considering both the mechanical step for the recovery of black mass, and the hydrometallurgical route for the recovery of metals. Black mass, recovered with high yield and purity by shredding, sieving and milling, was fed to leaching reactor for dissolving all metals (Li, Mn, Co, Ni) giving a residue which can be recovered as pure graphite. Co can be recovered as salt or oxide after precipitation by pH increase for metal impurity separation, or after solvent extraction achieving commercial purity. After separation of sodium, Li can be recovered as carbonate.

    Keywords:

    Hydrometallurgical; Leaching; Metal; Optimization; Recycling; Wastes;

    References:

    [1] X. Zeng, J. Li, N. Singh: Recycling of Spent Lithium-Ion Battery: A Critical Review, Crit. Rev. Env. Sci. Tec., 44 (2014), 1129–1165.
    [2] L. Chen, X. Tang, Y. Zhang, L. Li, Z. Zeng, Y. Zhang: Process for the recovery of cobalt oxalate from spent lithium-ion batteries, Hydrometallurgy 108 (2011), 80–86.
    [3] X. Wang, G. Gaustad, C.W. Babbitt, C. Bailey, M.J. Ganter, B.J. Landi: Economic and environmental characterization of an evolving Li-ion battery waste stream, J. Environ. Manage. 135 (2014), 126-134.
    [4] F. Pagnanelli, E. Moscardini, P. Altimari, T. Abo Atia, L. Toro: Leaching of electrodic powders from lithium ion batteries: optimization of operating conditions and effect of physical pretreatment for waste fraction retrieval, Waste Management, 60 (2017), 706-715.
    [5] F. Pagnanelli, E. Moscardini, P. Altimari, T. Abo Atia, L. Toro: Cobalt products from real waste fractions of end of life lithium ion batteries, Waste management, 51 (2016), 214- 221
    [6] G. Granata, E. Moscardini, F. Pagnanelli, F. Trabucco, L. Toro: Product recovery from lithium ion battery wastes coming from an industrial pre-treatment plant: lab scale tests and process simulations, J. Power Sources, 206 (2012), 393-401.
    [7] T. Abo Atia, P. Altimari, E. Moscardini, I. Pettiti, L. Toro, F. Pagnanelli: Synthesis and Characterization of Copper Ferrite Magnetic Nanoparticles for Heavy Metal Removal From Aqueous Solution. Proceedings of the International Conference on Nanotechnology based innovative applications for the environment, 20-23 March 2016, Rome, Italy Chemical Engineering Transactions n° 47, page 151-156 ISBN978-88-95608-38-9; ISSN2283-9216.

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    Cite this article as:

    Moscardini E, Altimari P, Toro L, Abo Atia T, Pagnanelli F, dos Santos Martins Padoan F. (2017). Recycling of Lithium Ion Batteries: Mechanical and Hydrometallurgical Treatment Towards Zero-waste. In Kongoli F, Aifantis K, Kumar V, Pagnanelli F, Kozlov P, Xueyi G (Eds.), Sustainable Industrial Processing Summit SIPS 2017 Volume 7. Recycling, Secondary Batteries and Environmental Protection (pp. 123-130). Montreal, Canada: FLOGEN Star Outreach