2018-Sustainable Industrial Processing Summit
SIPS2018 Volume 9. Energy Production, Secondary Battery

Editors:F. Kongoli, H. Dodds, M. Mauntz, T. Turna, V. Kumar, K. Aifantis
Publisher:Flogen Star OUTREACH
Publication Year:2018
Pages:170 pages
ISBN:978-1-987820-98-0
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
CD-SIPS2018_Volume1
CD shopping page

    Estimation of the Contents of Trace Elements in Shales in Connection with the Problems of Shale Development

    Svetlana Punanova1;
    1OIL AND GAS RESEARCH INSTITUTE OF THE RUSSIAN ACADEMY OF SCIENCES, Moscow, Russian Federation;
    Type of Paper: Regular
    Id Paper: 16
    Topic: 17

    Abstract:

    Priority directions of horizontal drilling in shale formations in the USA (Bakken, Barnett, Monterey, etc.) are considered. Growth and further development of this type of drilling in the territory of shale plays of the USA and other countries, as well as productive horizons of the Western Siberia, was noted. With a fairly detailed coverage in the domestic and foreign literature of all the pros and cons of shale horizontal drilling projects, and in particular the negative environmental consequences of hydraulic fracturing, the problem associated with the high content of metals and nonmetals in shales and oils is practically not considered. A significant number of them belong to the category of potentially toxic trace elements, dangerous for the habitat. The report presents the average trace elements content in the combustible and black shale from various basins of the world, the concentrations of a number of elements markedly exceeding in shale the clark content of clay rocks. High concentrations of a number of elements in the Kenderlik shale of the Republic of Kazakhstan, domanic deposits of the Volga-Ural oil and gas basin are shown, as well as some features of the distribution of radioactive elements and mercury in oils and shales. The release of toxic elements significantly increases with the thermal impact on the formation and some processes of hydrocarbon processing. In the case of hydraulic fracturing, it is possible that toxic elements from both shales and from the naphthides contained in them could be discharged to the environment. In the course of horizontal drilling, as with any other processes of impact on the reservoir, additional studies should be conducted to assess trace element composition of the shale formations and the hydrocarbons contained therein for monitoring environmental processes.

    Keywords:

    Drilling; Energy; Environment; Fuels; Oil; Petroleum; Radiation; Reservoirs; Spectroscopy;

    References:

    [1] Dvenadtsatova TI. 2015. The ecological back of the shale revolution: risks, bans and
    prospects. In: Neft’, Gaz i Pravo. № 6. Moscow (Russia). P. 36-46.
    [2] Dmitrievskii AN, Vysotskii VI. 2010. Shale gas: a new vector in the development of
    worldwide market of hydrocarbon raw materials. In: Gas industry. № 8. Moscow (Russia).
    P. 44-47.
    [3] Nemec R. 2016. Thriving in a Major U.S. Shale Play the Bakken Unpacked. In: Pipeline and
    Gas Journal. November. P. 56-60.
    [4] Johnson RC, Birdwell JE, Mercier TJ, Brownfield ME. 2016. Geology of Tight Oil and
    Potential Tight Oil Reservoirs in the Lower Part of the Green River Formation, Uinta,
    Piceance, and Greater Green River Basins, Utah, Colorado, and Wyoming. Scientific
    Investigations Report 2016. In: Geological Survey, Reston, Virginia (US). 75 р.
    [5] Punanova SA, Nukenov D. 2017. The question of environmental consequences at horizontal
    drilling of shale formations in connection with their enrichment with trace elemenrs. In:
    Georesources. Volume 19. № 3. Part 1. Kazan. Republic of Tatarstan (Russia). P. 239-248.
    [6] Ozdoev SM, Tsirel’tson BS. 2014. Oil shale of Kazakhstan. In: Oil and gas. № 1. Astana
    (Republic of Kazakhstan). P. 25-30.
    [7] Yakutseni SP. 2005. The abunance of hydrocarbons enriched with heavy element-impurities.
    Assessment of environmental risks. St.Petersburg: Nedra Publ. (Russia). 372 p.
    [8] Vinogradov AP. 1956. Regularities of distribution of chemical elements in the Earth’s crust.
    In: Geochemistry. Moscow (Russia). № 1. p. 6-52.
    [9] Ketris MP, YudovichYaE. 2009. Estimations of Clarkes for carbonaceous biolithes: World
    averages for trace element contents in black shales and coals. In: Int. J. Coal. Geol. Volume
    78. № 2. P. 135-148.
    [10] Kler VR, Nenakhova FYa, Saprykin FYa, Spirt MYa. 1988. Metallogeny and geochemistry
    of coal-bearing and shale-bearing strata of the USSR. Regularities of concentration of
    elements and methods of their study. Moscow: Nauka Publ. Moscow (Russia). 256 p.
    [11] Shpirt MYa, Punanova SA. 2012. Trace elements of caustobioliths. Problems of genesis and
    industrial use. Saarbrucken. (Germany): Lambert Academic Publishing. 367 p.
    [12] Zueva IN, Chalaya ON, Kashirtsev VA. et all. 2015. Possibilities of using high-carbon rocks
    of the Cuonam formation as a complex mineral raw material. In: Black shales: geology,
    lithology, geochemistry, significance for the oil and gas complex, prospects for using as an
    alternative hydrocarbon raw material: Proc. All-Russian Sci. and Pract. Conf. Ed. A.F.
    Safronov. Yakutsk (Russia): Akhsaan. P. 133-137.
    [13] Guide on the geochemistry of oil and gas. 1998. Ed. S.G. Neruchev. St.Petersburg: Nedra
    Publ. (Russia). 576 p.
    [14] Patterson JH, Dale LS, Fardy IJ. et al. 1987. Characterisation of trace elements in Rundle
    and Condor oil shales. In: Fuel. № 3. p. 319-322.
    [15] Mossman DJ, Gauthier-Lafaye F, Jackson S. 2005. Black shales, organic matter, ore genesis
    and hydrocarbon generation in the Paleoproterozoic Franceville Series, Gabon. In:
    Precambrian Research. Volume137. Issues 3-4. P. 253-272.
    [16] Wilhelm SM, Liang L, Cussen D, Kirchgessner A. 2007. Mercury in crude oil processed in
    the United States. In: Environmental Science and Technology. Volume 41. № 13. P. 4509-
    4514.
    [17] Kelly WR, Long SE, Mann JL. 2003. Determination of mercury in SRM crude oils and
    refined products by isotope dilution cold vapor ICP-MS using closed-system combustion.
    In: Anal. Bioanal. Chem. № 376. P. 753-758.
    [18] Shpirt MYа, Punanova SA. 2011. Accumulation of Mercury in Petroleum, Coal, and Their
    Conversion Products. In: Solid Fuel Chemistry. № 5. Moscow (Russia). P. 330-336.
    [19] Wilhelm SM. 2001. Estimate of Mercury Emissions to the Atmosphere from Petroleum. In:
    Environmental Science and Technology. Volume 35 (24). P. 4704-4710.
    [20] Shpirt MYa, Punanova SA. 2015. Mercury in caustobioliths: accumulation, burial and
    geoecology. In: Proc. Int. Conf. “Resource-reproducing, low-waste and nature protection
    technologies for subsoil development”. Bishkek (Kyrgyzstan). P. 158-159.
    [21] Shpirt MYa, Punanova SA. 2015. Radioactive Elements of Solid Fossil Fuels. In: Buck of
    Abstracts. 27-th International Meeting on Organic Geochemistry (IMOG 2015). Prague
    Praha (Czech Republic). P. 504.

    Full Text:

    Click here to access the Full Text

    Cite this article as:

    Punanova S. (2018). Estimation of the Contents of Trace Elements in Shales in Connection with the Problems of Shale Development. In F. Kongoli, H. Dodds, M. Mauntz, T. Turna, V. Kumar, K. Aifantis (Eds.), Sustainable Industrial Processing Summit SIPS2018 Volume 9. Energy Production, Secondary Battery (pp. 101-108). Montreal, Canada: FLOGEN Star Outreach