2019-Sustainable Industrial Processing Summit
SIPS2019 Volume 9: Tressaud Intl. Symp. / Solid State Chemistry for Applications and Sustainable Development
| Editors: | F. Kongoli, M.A. Alario Franco, J. Etourneau, S. Kalogirou, F.D.S. Marquis, R. Martins, K. Poeppelmeier, B. Raveau, Y. Shimakawa, M. Takano |
| Publisher: | Flogen Star OUTREACH |
| Publication Year: | 2019 |
| Pages: | 130 pages |
| ISBN: | 978-1-989820-08-7 |
| ISSN: | 2291-1227 (Metals and Materials Processing in a Clean Environment Series) |
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The Fascinating World of Fluoropolymers: From the Synthesis to Applications
Bruno Ameduri1; Mohammad Wehbi2;1INSTITUTE CHARLES GERHARDT MONTPELLIER, Montpellier, France; 2ICGM, Montpellier, France;
Type of Paper: Regular
Id Paper: 38
Topic: 52
Abstract:
Fluoropolymers are valuable materials endowed with outstanding properties that allow them to be involved in many High-Tech applications [1]. This presentation aims at reporting how the design of functional fluoropolymers may influence the properties and applications. Actually, 2-trifluoromethacrylic acid (MAF) is a versatile building block for the synthesis of new functional monomers. [2] It can be homopolymerized by anionic initiation [2-3] but fails in the presence of any radical systems. However, its radical copolymerization with vinylidene fluoride (VDF) has been successful. This presentation reports overall strategies to synthesize novel functional 2-trifluoromethacrylate monomers and macromonomers, as well as their radical copolymerization with VDF, leading to various materials such as higher thermal stable thermoplastics,[4] polymer gel electrolytes for Lithium ion batteries,[5-7] and anticorrosion [8] and adhesive hybrid coatings [9] (Figure 1).
Figure 1 shows the overall strategies to synthesize novel functional 2-trifluoromethyl monomers from 2-trifluoromethacrylic acid (MAF) and their radical copolymerization with VDF (left). The figure also shows steel plates coated with poly(VDF-co-MAF Phosphonate) copolymer at the beginning of the experiment (A), after 1 h (B), and after 18 h (C). (D): uncoated steel plate used as reference sample after 1 h (right).
Tosoh FineChem Corporation (Shunan, Japan) is acknowledged for suppling MAF monomers.
Keywords:
Advances in the synthesis routes; Design of materials for sustainable energy production;References:
[1] B. Ameduri, and H. Sawada; Fluoropolymers: Applications; vol. 2, RSC, Oxford, 2016.[2] Y. Patil and B. Ameduri, Progr. Polym. Sci., 38 (2013), 703-739.
[3] T. Narita, a) Makromol. Chem. Rapid. 6 (1985) 301-304; b) J. Fluorine Chem. 131 (2010), 812.
[4] M. Wadekar, Y. Patil, B. Ameduri, Macromolecules, 47 (2014) 47, 13-25.
[5] A. Alaeddine, J. Vergnaud, D. Vlad, J.F. Gohy, B. Ameduri, Polym. Chem. 6 (2015) 6021-6032.
[6] M. Wehbi, J. F. Gohy et al. J. Mat Chem. A, 6 (2018) 8514-8526.
[7] M. Wehbi, J. Brassine, et al., Macromolecules, 52 (2019) DOI: 10.1021/acs.macromol.9b00355.
[8] S. Banerjee, M. Wehbi et al., ACS Appl. Mater. Interface, 9 (2017) 6433-6443.
[9] M. Wehbi, S. Banerjee, et al., Macromolecules, 50 (2017) 50, 9329-9339.