2025 - Sustainable Industrial Processing Summit
SIPS2025 Volume 5. Meyers Intl. Symp. / Composite

Editors:F. Kongoli, P. Assis, H.A.C. Lopera, S. Diaz, S.N. Monteiro, V.S. Candido
Publisher:Flogen Star OUTREACH
Publication Year:2025
Pages:316 pages
ISBN:978-1-998384-46-4 (CD)
ISSN:2291-1227 (Metals and Materials Processing in a Clean Environment Series)
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    FABRICATION OF PARTICLE-FREE SILVER INK AND ITS APPLICATION TO LOW-TEMPERATURE SINTERABLE HIGH-CONDUCTIVITY PASTE

    Jong-Hyun Lee1;
    1SEOUL NATIONAL UNIVERSITY OF SCIENCE AND TECHNOLOGY, Seoul, South Korea;
    Type of Paper: Regular
    Id Paper: 214
    Topic: 18

    Abstract:

     In addition to conventional applications in the printing of electrodes or antenna patterns on low-cost polymer substrates, the application of low-temperature sinterable Ag pastes is now also being explored for electrode fabrication in perovskite solar cells. In this study, a particle-free Ag ink was synthesized based on an Ag-organic complex, and a printable paste capable of sintering at 120 °C was formulated by adding Ag flakes. The corresponding properties were systematically evaluated. For the optimization of ink formulation, the optimal combination of Ag salt and amine-based complexing agents was determined, and a solvent exhibiting both rapid evaporation at low temperatures and synergistic compatibility with the complex system was selected, enabling film formation at 120 °C. Subsequently, after the optimal amount of Ag flakes was incorporated, the resistivity of the film decreased with increasing annealing time at 120 °C, ultimately achieving an excellent electrical resistivity of 1.13 × 10⁻⁵ Ω·cm after 90 min. However, after 120 minof annealing, the resistivity increased to 1.19 × 10⁻⁴ Ω·cm, which was attributed to the formation of large pores in the microstructure during the grain growth process [1].

    Keywords:

    Ag complex ink; High-Conductivity Paste; Low-temperature sintering; Electrical resistivity; Grain growth

    Cite this article as:

    Lee J. (2024). FABRICATION OF PARTICLE-FREE SILVER INK AND ITS APPLICATION TO LOW-TEMPERATURE SINTERABLE HIGH-CONDUCTIVITY PASTE. In F. Kongoli, P. Assis, H.A.C. Lopera, S. Diaz, S.N. Monteiro, V.S. Candido (Eds.), Sustainable Industrial Processing Summit Volume 5 Meyers Intl. Symp. / Composite (pp. 291-292). Montreal, Canada: FLOGEN Star Outreach