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    [Solid and liquid wastes from industrial processes: Innovations in material recovery and environmental protection]
    ZERO WASTE PROCESSING OF ZINC CONTAINING SLAGS FROM LEAD INDUSTRY
    ZERO WASTE PROCESSING OF ZINC CONTAINING SLAGS FROM LEAD INDUSTRY
    Juergen Antrekowitsch1;
    1CHRISTIAN DOPPLER LABORATORY, Leoben, Austria;
    PAPER: 368/Recycling/Plenary (Oral) OS
    SCHEDULED: 14:00/Tue. 28 Nov. 2023/Sunflower



    ABSTRACT:

    Slags from primary lead industry are well known as potential resource for zinc which is accumulated in the slag during lead smelting. At some of the smelters a subsequent fuming process is installed to recover zinc which is usually present in a range between 4 to 16 %.

    However, at many lead producers this is not the case and the slag is landfilled. Out of this, over the years, a huge number of dumps was generated worldwide. The Chair of Nonferrous Metallurgy at Montanuniverstaet Leoben has developed possible strategies to treat such slags in a way that zinc and lead can be recovered and the remaining mineral phase containing first of all typical slag components can also be utilized. These concepts allow a full remediation of a dumpsite or a zero waste treatment of slag from ongoing smelter operations.

    The present paper describes the reduction process which is performed under CO2-neutral conditions, utilizing either hydrogen or charcoal. Furthermore, possibilities for slag modification and optimization are explained, allowing a utilization of the slag in building and construction industry. Results from various test campaigns in lab- and technical scale are discussed.

    Finally, an overview of the worldwide potential and some process scenarios including economic considerations are presented.



    References:
    [1] Auer M., C. Wölfler and J. Antrekowitsch: Inflluence of different carbon content on reduction of zinc oxide via metal bath. Applied Sciences (2022), 12, 2, 4180<br />[2] Hanke G., J. Antrekowitsch, F. Castro and H. Krug: Maximizing the efficiency of by-product treatment by multi-metal recovery and slag valorization. Rewas 2022 – Developing tomorrow‘s technical cycles (2022), Anaheim, Kalifornien, USA, 201–211<br />[3] Leuchtenmueller M., C. Legerer, U. Brandner U. and J. Antrekowitsch: Carbothermic Reduction of Zinc Containing Industrial Wastes: A Kinetic Model, Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science (2021), 548-557