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    REDUCTION RATE ENHANCEMENT OF CARBON COMPOSITE IRON OXIDE PELLETS BY USING SEMI-CHAR OR SEMI-CHARCOAL
    Tateo Usui1; Hirokazu Konishi2; Kazuhira Ichikawa3; Hideki Ono4; Hirotoshi Kawabata2; Paulo Assis5;
    1OSAKA UNIVERSITY, Ibaraki, Japan; 2OSAKA UNIVERSITY, Suita, Japan; 3JFE STEEL CORPORATION, Fukuyama, Japan; 4UNIVERSITY OF TOYAMA, Toyama, Japan; 5UFOP, OURO PRETO, Ouro Preto, Brazil;
    PAPER: 424/Iron/Regular (Oral) OS
    SCHEDULED: 15:15/Tue. 28 Nov. 2023/Dreams 2



    ABSTRACT:

    The exhaustion of natural resources (quantity and quality) and CO2 emission controls are becoming increasingly important in steel industry.  A lot of steel engineers studied various means to decrease reducing agent at blast furnace for reduction of CO2 emissions.  For example, injection of waste plastics and carbon neutral materials such as biomass into blast furnace is better alternative. Especially, biomass has novel advantage, namely, no CO2 emissions, because of carbon neutral. Production of carbon composite iron ore agglomerates having good reducibility and strength is becoming one of the most important subjects. 

         Carbon composite iron oxide pellets using semi-char or semi-charcoal were proposed in order to enhance the reduction rate of iron oxide.  The carbonization was done under a rising temperature condition until arriving at a maximum carbonization temperature Tc,max to release some part of the volatile matter included (V.M.).  Starting point of reduction of carbon composite pellet using semi-charcoal produced at Tc,max = 823 K under the rising reduction-temperature condition was observed at the reduction temperature TR = 833 K, only a little higher than Tc,max (823 K), which was the aimed phenomena.  As Tc,max increases, the emitted carbonization gas volume increases, while the residual V.M. decreases, and, as a whole, the total heat value of the carbonization gas emitted tends to increase monotonically.



    References:
    [1] Tateo Usui, Hirokazu Konishi, Kazuhira Ichikawa, Hideki Ono, Hirotoshi Kawabata, Francisco B. Pena, Matheus H. Souza, Alexandre A. Xavier and Paulo S. Assis, “Evaluation of Carbonisation Gas from Coal and Woody Biomass and Reduction Rate of Carbon Composite Pellets”, Advances in Materials Science and Engineering, Vol.2018, Article ID 3807609, 2018, pp.1-14<br />[2] . Konishi, T. Usui and K. Azuma, “The Preparation and Reduction Behavior of Carbon Composite Iron Oxide Pellets Using Semi-coal- char”, Tetsu-to-Hagané, 92, 2006, pp.802-808.<br />[3] H. Konishi, A. Yamashita and T. Usui, “Effect of Residual Volatile Matter on Reduction of Iron Oxide in Carbon Composite Pellets”, Journal of JSEM (Japanese Society for Experimental Mechanics), 8, 2008, Special Issue, pp.142-146.<br />[4] H. Konishi, T. Usui and A. Yamashita, “Effect of Residual Volatile Matter on Reduction Reaction between Semi-coal-char and Iron Oxide”, Tetsu-to-Hagané, 95, 2009, pp.467-472.<br />[5] H. Konishi, K. Ichikawa and T. Usui, “Effect of Residual Volatile Matter on Reduction of Iron Oxide in Semi-charcoal Composite Pellets”, ISIJ International, 50, 2010, pp.386-389.<br />[6] H. Konishi, T. Usui and T. Harada, “The Preparation and Reduction Behavior of Charcoal Composite Iron Oxide Pellets”, Journal of High Temperature Society, 34, 2008, pp.14-19.<br />[7] H. Konishi, S. Fujimori and T. Usui, “Reduction Behavior of Iron Oxide in Semi-charcoal Composite Pellets”, Journal of High Temperature Society, 35, 2009, pp.33-39.<br />[8] T. Ariyama and M. Sato, “Optimization of Ironmaking Process for Reducing CO2 Emissions in the Integrated Steel Works”, ISIJ International, 46, 2006, pp.1736-1744.<br />[9] M. Asanuma et al., “Development of Waste Plastics Injection Process in Blast Furnace”, ISIJ International, 40, 2000, pp.244-251.<br />[10] T. Ariyama, R. Murai, J. Ishii and M. Sato, “Reduction of CO2 Emissions from Integrated Steel Works and Its Subject for a Future Study”, ISIJ International, 45, 2005, pp.1371-1378.<br />[11] T. Matsumura, M. Ichida, T. Nagasaka and K. Kato, “Carbonization Behaviour of Woody Biomass and Resulting Metallurgical Coke”, ISIJ International, 48, 2008, pp.572-577.<br />[12] M. Nakano, M. Naito, K. Higuchi and K. Morimoto, “Non-spherical Carbon Composite Agglomerates: Lab-scale Manufacture and Quality Assessment”, ISIJ International, 44, 2004, pp.2079-2085.