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IMPROVING BIOCOKE FOR INCREASED APPLICABILITY IN METALLURGY
Juergen Antrekowitsch1; Gustav Hanke2; Tendai Nyangadzayi3
1Chair of Nonferrous Metallurgy, University of Leoben, Leoben, Austria; 2Montanuniversität Leoben, Leoben, Austria; 3Montanuniversitaet Leoben, Leoben, Austria

PAPER: 283/Carbon/Plenary (Oral) OS
SCHEDULED: 13:00/Thu. 20 Nov. 2025/Lotus

ABSTRACT:

The use of biocoke in metallurgical processes to reduce the carbon footprint of metal production has gained significant traction in recent years. This trend is particularly evident in Central Europe, where biocoke production has grown rapidly. While utilization of biocoke has already become standard in certain processes, such as ferroalloy production, its implementation in other metallurgical routes remains challenging.

Key limitations include its high surface area and reactivity, low mechanical strength, and low bulk density. These properties often make even partial substitution of fossil carbon infeasible - especially in systems like rotary kilns, small shaft furnaces or vertical retorts. In such setups, the reducing agent undergoes a pre-heating phase and ideally remains inert for one to two hours before entering the reduction zone. Under these conditions, conventional biocoke is ineffective.

At the Chair of Nonferrous Metallurgy, Technical University of Leoben, new strategies have been developed to tailor the properties of pyrolyzed biomass for metallurgical use. Through advanced micro-granulation combined with small quantities of special additives, reactivity can be reduced by at least 50%. This treatment also enhances density and improves performance in possible subsequent agglomeration processes such as briquetting.

REFERENCES:
[1] Griessacher T., J. Antrekowitsch und S. Steinlechner: Charcoal from agricultural residues as alternative reducing agent in metal recycling. Biomass and Bioenergy 39 (2012), 139 – 146
[2] Agirre Arisketa I., T. Griessacher, A. Adrados, J. Requies, J. Cambra und J. Antrekowitsch: Catalytic upgrading of biomass pyrolysis vapors to bio-syngas, a possible reducing agent for metallurgical processes. Proc. of 4th International Conference on Engineering for Waste and Biomass Valorisation (2012), Porto, Portugal