2018 - Sustainable Industrial Processing Summit & Exhibition
4-7 November 2018, Rio Othon Palace, Rio De Janeiro, Brazil
Seven Nobel Laureates have already confirmed their attendance: Prof. Dan Shechtman, Prof. Sir Fraser Stoddart, Prof. Andre Geim, Prof. Thomas Steitz, Prof. Ada Yonath, Prof. Kurt Wüthrich and Prof. Ferid Murad. More than 400 Abstracts Submitted from about 60 Countries.
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    Advantages of Using Low Alkali Cements and Industrial Waste Materials in Prevention of Alkali-silica Reaction in Concrete
    Cibele Sanchez Roboredo1; Paul Thomas2; Kirk Vessalas2; Vute Sirivivatnanon2;
    1, Sydney, Australia; 2UNIVERSITY OF TECHNOLOGY SYDNEY, Sydney, Australia;
    PAPER: 238/Non-ferrous/Regular (Oral)
    SCHEDULED: 17:40/Mon./Pontal (50/2nd)



    ABSTRACT:
    Manufactured cement has to comply with the requirement of containing less than 0.60% sodium oxide equivalent (Na<sub>2</sub>Oeq) to meet the standard alkali content specified by codes of practices worldwide, such as ASTM C150 [1]. This limit has been adopted since the 1940s for the purpose of preventing deleterious expansion due to alkali-silica reaction (ASR), which has the potential to compromise the mechanical performance of concrete structures in service. Limiting the amount of sodium and potassium alkalis in cement is one method of lowering the alkali content [2]. However, raw materials used to manufacture cement may often contain alkali contents exceeding this limit. These raw materials are thus often discarded for use in cement manufacture. Another challenge to contend with is the need to conserve naturally occurring resources. Therefore, alternative solutions proposing the use of industrial by-products raw materials need to be considered [3].<br />The use of supplementary cementitious materials (SCMs), like fly ash and slag, generated as industrial waste can be recycled in blended cements [4], which provides a viable option for lowering the alkali content of cement permitting the use of raw materials that would otherwise be discarded to landfill. This paper reviews the advantages of using SCMs to lower the alkali content of cement and allow a wider range of raw materials to be employed in cement manufacture whilst conserving natural resources and decreasing the CO<sub>2</sub> emissions associated with cement manufacture [5].

    References:
    [1] Kerenidis, K.; Hooton, R. D., Mitigating alkali-silica reaction when using high-alkali cements. Concrete International 2011, 33 (5), 34-39.<br />[2] Hill, E. D., Alkali limits for prevention of alkali-silica reaction: A brief review of their development. Cement, Concrete, and Aggregates 1996, 18 (1), 3-7.<br />[3] Thomas, M., The effect of supplementary cementing materials on alkali-silica reaction: A review. Cement and Concrete Research 2011, 41 (12), 1224-1231.<br />[4] Hill, E. D., Alkali limits for prevention of alkali-silica reaction: A brief review of their development. Cement, Concrete, and Aggregates 1996, 18 (1), 3-7.<br />[5] Barker, D. J.; Turner, S. A.; Napier-Moore, P. A.; Clark, M.; Davison, J. E., CO2 Capture in the Cement Industry. Energy Procedia 2009, 1 (1), 87-94.