2018 - Sustainable Industrial Processing Summit & Exhibition
4-7 November 2018, Rio Othon Palace, Rio De Janeiro, Brazil
Seven Nobel Laureates have already confirmed their attendance: Prof. Dan Shechtman, Prof. Sir Fraser Stoddart, Prof. Andre Geim, Prof. Thomas Steitz, Prof. Ada Yonath, Prof. Kurt Wüthrich and Prof. Ferid Murad. More than 400 Abstracts Submitted from about 60 Countries.
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    Solution-based Synthesis of Li<sub>3</sub>PS<sub>4</sub> Solid Electrolytes
    Hee-dae Lim1; Xing Xing2; Ping Liu2;
    1KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY (KIST), Seoul, South Korea; 2UNIVERSITY OF CALIFORNIA, SAN DIEGO (UCSD), San Diego, United States;
    PAPER: 384/Battery/Regular (Oral)
    SCHEDULED: 14:25/Mon./Asian (60/3rd)



    ABSTRACT:
    Sulfide-based solid electrolytes have attracted much attention due to their high conductivities, which are far beyond those of oxide-based solid electrolytes. [1,2] However, They (Li<sub>2</sub>S-P<sub>2</sub>S<sub>5</sub> system, i.e., LPS) have been normally synthesized by solid state synthesis such as mechanical ball milling. These methods require rigorous control of reaction environment as well as high temperature heat treatment and repeated pelletizing steps. In contrast, solution-based synthesis methods can induce chemical reaction among precursor particles (Li<sub>2</sub>S and P<sub>2</sub>S<sub>5</sub>) at low temperatures resulting in the formation of conductive phases of Li<sub>3</sub>PS<sub>4</sub> and Li<sub>3</sub>P<sub>7</sub>S<sub>11</sub> with only moderate thermal treatment.[3,4] The method deserves great attention since it simplifies synthesis process, yields products of great purity, and may facilitate the fabrication of composite electrodes with improved interfaces. <br />In this work, we have developed an efficient method to form a thin solid electrolyte layer directly on Li metal using the liquid coating techniques. The formation of LPS (Li<sub>2</sub>S-P<sub>2</sub>S<sub>5</sub>) based electrolyte is achieved by rational design of the solvent and the Li, P, and S precursor ratios. The solution electrolyte can be directly coated and formed on Li metal through the in-situ formation of the solid electrolyte layer, which does not require the complex synthesis process and high temperature sintering step. Layers of thickness of < 50 um can be fabricated and electrochemical cycling of lithium is achieved. This liquid-phase coating is a simple and straightforward technique for making a thin solid electrolyte and can be applicable to anode surface with complex contours. The new liquid coating technique holds the promise to overcome the limitations of current state solid electrolytes.

    References:
    [1] Kamaya, N. et al. A lithium superionic conductor. Nature Mater. 10, 682-686 (2011).<br />[2] Yamane, H. et al. Crystal structure of a superionic conductor, Li7P3S11. Solid State Ion. 178, 1163-1167 (2007).<br />[3] Ito, S. et al. A synthesis of crystalline Li7P3S11 solid electrolyte from 1,2-dimethoxyethane solvent. J. Power Sources 271, 342-345 (2014).<br />[4] Liu, Z. et al. Anomalous High Ionic Conductivity of Nanoporous Li3PS4. J. Am. Chem. Soc. 135, 975-978 (2013).